IX-C-1 Bridging Nano-Gap Electrodes by In Situ Electropolymerization of a Bis-
نویسندگان
چکیده
A novel 3,8-bis-terthiophenyl-(1,10-phenanthroline) coordinated to [Ru(bpy)2] was synthesized and characterized by electrochemical and spectroscopic techniques, and shown to be a suitable starting material for the electrodeposition of functionalized molecular wires in between nano-gap electrodes, generating stable molecular nano-devices. Temperature dependent nonlinear I-V curves were obtained in the 80 to 300 K range. The material can be deposited on ITO also, forming compact electrochromic films at surface concentrations lower than about 1 × 10–8 mol·cm2, but a more loosely bond fibrous form is preferentially deposited at higher surface concentrations.
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